邹梦圆, 董红敏, 朱志平, 占源航, 尹福斌, 张万钦, 曹起涛. 惰性填料种类对猪场沼液氨吹脱效果的影响[J]. 农业工程学报, 2018, 34(23): 186-192. DOI: 10.11975/j.issn.1002-6819.2018.23.023
    引用本文: 邹梦圆, 董红敏, 朱志平, 占源航, 尹福斌, 张万钦, 曹起涛. 惰性填料种类对猪场沼液氨吹脱效果的影响[J]. 农业工程学报, 2018, 34(23): 186-192. DOI: 10.11975/j.issn.1002-6819.2018.23.023
    Zou Mengyuan, Dong Hongmin, Zhu Zhiping, Zhan Yuanhang, Yin Fubin, Zhang Wanqin, Cao Qitao. Effect of different types of sluggishness packings on ammonia stripping of piggery biogas slurry[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2018, 34(23): 186-192. DOI: 10.11975/j.issn.1002-6819.2018.23.023
    Citation: Zou Mengyuan, Dong Hongmin, Zhu Zhiping, Zhan Yuanhang, Yin Fubin, Zhang Wanqin, Cao Qitao. Effect of different types of sluggishness packings on ammonia stripping of piggery biogas slurry[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2018, 34(23): 186-192. DOI: 10.11975/j.issn.1002-6819.2018.23.023

    惰性填料种类对猪场沼液氨吹脱效果的影响

    Effect of different types of sluggishness packings on ammonia stripping of piggery biogas slurry

    • 摘要: 氨吹脱作为猪场沼液的预处理方法,其处理效果受填料等多种因素的影响。分别采用空心多面球、鲍尔环和流化床填料在pH值10.5,气液比2 000,温度30 ℃的条件下吹脱猪场沼液,结果表明:空心多面球和流化床对沼液氨氮(ammonia nitrogen,NH4+-N)的平均去除率显著高于鲍尔环填料(P<0.05),吹脱2 h,氨氮的平均去除率分别为80.7%、59.0%和77.4%。投加NaOH使沼液化学需氧量(chemical oxygen demand,COD)因压缩双电层和混凝而降低,总固体(total solid,TS)和挥发性固体(volatile solid,VS)因OH-对微生物结构的破坏和大分子物质的水解而增加。吹脱过程使COD部分提高,而TS和VS有所降低。3种填料的性能参数差异导致吹脱后沼液COD平均去除率的变化和VS的平均去除率不同,但不存在显著差异(P>0.05),流化床填料对TS的平均去除率显著高于空心多面球(P<0.05)。选定空心多面球吹脱20 L沼液2 h,1 L的1 mol/L硫酸吸收液对吹脱尾气中氨气的平均吸收率为35.8%,兼顾吸收效果和经济性。

       

      Abstract: Abstract: The treatment effect of ammonia stripping which is a pretreatment method of piggery biogas slurry is affected by many factors including pH value, temperature, air liquid ratio and packings etc. On the basis of previous studies, ammonia stripping effects of piggery biogas slurry in polyhedral hollow ball, pall ring and fluidized bed packing were studied in this article. Effects of adding sodium hydroxide and stripping in different types of packings on chemical oxygen demand, total solid and volatile solid of biogas slurry were also discussed. 50 L piggery biogas slurry which had been pretreated by flocculation, solid-liquid separation and paper tape filtration in turn was added to each tank. The same volume of polyhedral hollow ball packing, pall ring packing and fluidized bed packing were loaded in the air stripping tower respectively. The packings material are polypropylene plastics, whose diameter are both 25 mm. Biogas slurry was stripped for 5 hours under the conditions with pH value of 10.5, air liquid ratio of 2 000 and temperature of 30 ℃. 150 mL sample was taken from the tank every half hour during the stripping process. The stripping effects in different types of packings were analyzed. The results showed that the ammonia nitrogen average removal rates in polyhedral hollow ball packing and fluidized bed packing were significantly higher than that of pall ring packing (P<0.05) and the ammonia nitrogen average removal rates were 80.7%, 59.0% and 77.4%, respectively, when the air stripping tower ran for 2 hours. Considering the operational energy consumption and ammonia nitrogen and total nitrogen removal effects, polyhedral hollow ball packing was selected as the preferred material. The operation time should be controlled within 2 hours. The chemical oxygen demand of biogas slurry partial decreased on account of the compression of the twin electrical layer and coagulation after adding sodium hydroxide. The total solid and volatile solid of biogas slurry both increased because of the destruction of microorganism structure and the hydrolysis of macromolecular matters after adding sodium hydroxide. The chemical oxygen demand of biogas slurry partial increased, meanwhile, the total solid and volatile solid both decreased after ammonia stripping. The variations of chemical oxygen demand average removal rates and volatile solid average removal rates were different as a result of the differences in performance parameters of three types of packings, but they had no significant differences in three types of packings (P>0.05). The total solid average removal rate in fluidized bed packing was significantly higher than that of polyhedral hollow ball packing (P<0.05). 20 L piggery biogas slurry was stripped for 2 hours under the conditions with pH value of 10.5, air liquid ratio of 2 000 and temperature of 30 ℃ in polyhedral hollow ball packing and stripped ammonia was absorbed by 1 L sulfuric acid of 1, 1.5 and 2 mol/L, respectively. The average absorption rates were 35.8%, 36.7% and 32.4%, respectively, and they had no significant differences (P>0.05). Considering the absorption effect and economy, 1 mol/L sulfuric acid was selected as the preferred absorbent to absorb stripped ammonia.

       

    /

    返回文章
    返回