成亮, 周建斌, 章一蒙, 田霖, 马欢欢, 宋建忠, 张齐生. 糠醛渣和废菌棒的热解气化多联产再利用[J]. 农业工程学报, 2017, 33(21): 231-236. DOI: 10.11975/j.issn.1002-6819.2017.21.028
    引用本文: 成亮, 周建斌, 章一蒙, 田霖, 马欢欢, 宋建忠, 张齐生. 糠醛渣和废菌棒的热解气化多联产再利用[J]. 农业工程学报, 2017, 33(21): 231-236. DOI: 10.11975/j.issn.1002-6819.2017.21.028
    Cheng Liang, Zhou Jianbin, Zhang Yimeng, Tian Lin, Ma Huanhuan, Song Jianzhong, Zhang Qisheng. Re-utilization of furfural residues and wasted mushroom inoculation bags by multi-production gasification technology[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2017, 33(21): 231-236. DOI: 10.11975/j.issn.1002-6819.2017.21.028
    Citation: Cheng Liang, Zhou Jianbin, Zhang Yimeng, Tian Lin, Ma Huanhuan, Song Jianzhong, Zhang Qisheng. Re-utilization of furfural residues and wasted mushroom inoculation bags by multi-production gasification technology[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2017, 33(21): 231-236. DOI: 10.11975/j.issn.1002-6819.2017.21.028

    糠醛渣和废菌棒的热解气化多联产再利用

    Re-utilization of furfural residues and wasted mushroom inoculation bags by multi-production gasification technology

    • 摘要: 糠醛渣和废菌棒是农林木质纤维素类生物质经利用后的废弃物。该文分析了糠醛渣和废菌棒的组分构成和热失重特性,并以糠醛渣和废菌棒为原料,以生物质高效无污染全面利用为目的,应用生物质气化多联产技术制备了生物质炭与可燃气。糠醛渣的C元素含量较高而挥发分含量较低,糠醛渣的热值(20.87 MJ/kg)高于废菌棒(18.01 MJ/kg)。糠醛渣的半纤维素失重肩峰明显消失,其最大质量损失速率高于废菌棒,质量损失总量低于废菌棒。糠醛渣和废菌棒的气化产炭率分别为29.99%和22.26%,糠醛渣炭的热值为26.18 MJ/kg,高于废菌棒炭的20.09 MJ/kg,糠醛渣炭的比表面积为253.58 m2/g,高于废菌棒炭的189.08 m2/g。糠醛渣可燃气和废菌棒可燃气的产率分别为2.49和2.25 m3/kg,其热值含量基本处于同一水平,分别为4.86和4.92 MJ/m3。糠醛渣和废菌棒可分别用于机制炭和炭基肥料等的生产,同时产出生物质可燃气。

       

      Abstract: Abstract: Furfural residues and wasted mushroom inoculation bags are the wastes from utilized lignocellulosic agricultural/ forestry residues. There were 240-300 million tons of furfural residues and 1500 million tons of wasted mushroom inoculation bags generated in China every year, but they were not disposed well and caused environmental problems. In order to reuse these wasted biomasses thoroughly and cleanly, the multi-production gasification technology was adopted in this study to convert furfural residues and wasted mushroom inoculation bags into bio-carbon and bio-based combustion gas. The component properties of furfural residues and wasted mushroom inoculation bags as well as their products (bio-carbon and bio-based combustion gas) were also analyzed, correspondingly. Compared to the wasted mushroom inoculation bags (11.14%), the ash content of furfural residues was lower (8.75%). The volatile content of furfural residues (66.05%) was lower than wasted mushroom inoculation bags (68.37%), whereas the fixed carbon content of furfural residues (25.21%) was higher than wasted mushroom inoculation bags (20.50%). The C content of furfural residues was 53.04% which was higher than the wasted mushroom inoculation bags (42.55%), whereas the contents of H (1.71%), O (35.14%), N (0.62%) and S (0.73%) of furfural residues were all lower than wasted mushroom inoculation bags (2.61%, 40.72%, 1.34% and 0.86%, respectively.) The heating value of furfural residue was 20.87 MJ/kg, higher than wasted mushroom inoculation bags (18.01 MJ/kg). From thermogravimetric (TG) analysis, the differential thermogravimetric (DTG) shoulder peak caused by hemicellulose disappeared for furfural residues, and its maximum weight loss rate was higher but total weight loss was lower than wasted mushroom inoculation bags. The bio-carbon yields of furfural residues and wasted mushroom inoculation bags were 29.99% and 22.26%, respectively. Considering that the ignition and shutdown process of the gasifier will lead to an excessive gasification and consumption of the bio-carbon, and the feeding amount of the materials in this study was limited, the yield of the bio-carbon and bio-based combustion gas will be higher in continuous industrial production process. The ash and volatile contents of the bio-carbon generated from furfural residues were 22.49% and 5.56%, respectively, significantly lower than that from the wasted mushroom inoculation bags (47.04% and 10.94%), whereas the fixed carbon content of bio-carbon generated from furfural residues was much higher (70.73%) than that from the wasted mushroom inoculation bags (42.02%). For the elements, only N content of the bio-carbon generated from furfural residues (0.57%) was lower than that from wasted mushroom inoculation bags (1.07%). The heating values of the bio-carbon generated from furfural residues and wasted mushroom inoculation bags were 26.18 and 20.09 MJ/kg, and their specific surface areas were 253.58 and 189.08 m2/g, respectively. Compared to bio-carbon generated from rice straw, cotton stalk and corn stalk, the furfural residue bio-carbon has good potential to be used as the raw material for the activated carbon production, whereas the bio-carbon from wasted mushroom inoculation bags can be good material to produce carbon-based fertilizer. The bio-based combustion gas yields of furfural residues and wasted mushroom inoculation bags were 2.49 and 2.25 m3/kg, respectively, and their heating values were 4.86 and 4.92 MJ/m3, respectively.

       

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