潘碌亭, 谢欣珏, 王九成, 董恒杰. 脱氮除磷生物滤池填料制备及其对农村生活污水的处理效果[J]. 农业工程学报, 2017, 33(9): 230-236. DOI: 10.11975/j.issn.1002-6819.2017.09.030
    引用本文: 潘碌亭, 谢欣珏, 王九成, 董恒杰. 脱氮除磷生物滤池填料制备及其对农村生活污水的处理效果[J]. 农业工程学报, 2017, 33(9): 230-236. DOI: 10.11975/j.issn.1002-6819.2017.09.030
    Pan Luting, Xie Xinjue, Wang Jiucheng, Dong Hengjie. Preparation of denitrification and dephosphorization biological fillers and its effect on treatment of rural domestic sewage[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2017, 33(9): 230-236. DOI: 10.11975/j.issn.1002-6819.2017.09.030
    Citation: Pan Luting, Xie Xinjue, Wang Jiucheng, Dong Hengjie. Preparation of denitrification and dephosphorization biological fillers and its effect on treatment of rural domestic sewage[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2017, 33(9): 230-236. DOI: 10.11975/j.issn.1002-6819.2017.09.030

    脱氮除磷生物滤池填料制备及其对农村生活污水的处理效果

    Preparation of denitrification and dephosphorization biological fillers and its effect on treatment of rural domestic sewage

    • 摘要: 针对农村生活污水处理过程中,总氮(TN)和总磷(TP)难以直接达到《城镇污水处理厂污染物排放标准》(GB18918-2002)一级A排放标准的难题,该研究研制出一种新型脱氮除磷滤料,并对其表征。扫描电镜结果表明该滤料亲水性较好,表面粗糙,大量的空隙和较大的比表面积利于微生物挂膜;光学显微镜观察结果表明,生物膜生长状况良好,活性较高,无需反冲洗就能长期稳定运行。将该新型滤料用于两级生物滤池对农村生活污水的处理研究,考察了水力停留时间(hydraulic retention time,HRT)、气水比、回流比及温度对系统TN和TP处理效果的影响。研究发现,在一定范围内,污染物质的去除率与水力停留时间和温度成正相关,随着气水比和回流比的增大先上升后下降;温度对TN去除的影响较为显著。试验得出系统运行的最适工况:HRT 5 h,气水比10:1,回流比50%,最利于系统脱氮温度为27 ℃。系统在最佳试验条件下稳定运行后,出水COD(化学需氧量)、NH3-N、TN和TP平均质量浓度分别为18.53、0.66、9.78、0.30 mg/L,平均去除率分别为89.82%、99.80%、59.05%、88.31%,满足《城镇污水处理厂污染物排放标准》一级A排放标准要求。研究结果可为实际工程和理论研究提供参考。

       

      Abstract: Abstract: In the treatment of the rural domestic sewage, the total nitrogen(TN) and total phosphorus(TP) effluent concentration has been too high to comply with the class A of Pollutant Discharge Standard of Municipal Wastewater Treatment Plan(GB18918-2002). To solve this problem, a new type of denitrification and dephosphorization filer adopted in an anoxic filter (AF) - biological aerated filter (BAF) system was developed. The mass percentage of the raw materials of this fillers, namely steel slag, iron scrap, zeolite, activated carbon and cement, was 45%, 10%, 20%, 10% and 15%, respectively. The mixture of these materials at this mass ratio was then wrapped on the hollow float in the coating machine. The final product was produced after curing for a certain time. Due to the fact that the new fillers presented excellent synchronous nitrogen and phosphorus removal performances and were easy to prepare with low cost, they could be beneficial for promotion and application. The scanning electron microscope (SEM) results demonstrated that the fillers were of good hydrophilicity and rough surface. A large number of voids and large specific surface area was conductive to biofilm colonization. Optical microscope results showed that the biofilm was of good growth and high activity, which could remain long-term stable operation without backwash. And five main influencing factors (HRT, gas water ratio, reflux ratio and temperature) were investigated for the advanced treatment research. In the single factor experiment, when the value of the study factor was changed, TN and TP concentrations were measured for consecutive 4 days after the system got stable, and the average value was taken as the final result. The results showed that, within a certain range, the pollutants removal rate was proportional to HRT and temperature which means that the improvement of HRT and temperature exerted a positive effect on pollutant removal within a certain range. Besides, the removal rate tended to increase at first and then decrease with the rising of gas water ratio and reflux ratio. At the same time, the TN removal efficiency was significantly affected by temperature. The TN removal rate experienced an upward then a following downward trend with the increasing of temperature. In contrast, the TP removal rate increased slightly as temperature rose, drawing the conclusion that the changes of temperature had little effect on TP removal. Overall, the optimum conditions of this technology were as follows: HRT 5h, gas water ratio 10:1, reflux ratio 50% and 27℃, which was best for the nitrogen removal. With a stable system operation achieved, the effluent COD (chemical oxygen demand), NH3-N, TN and TP were 18.53, 0.66, 9.78 and 0.30 mg/L respectively and the removal efficiencies were 89.82%, 99.80%, 59.05% and 88.31%, respectively, which could meet the A class criteria specified in Pollutant Discharge Standard of Municipal Wastewater Treatment Plan(GB18918-2002). Through the comparative test conducted, the effect of the new filters was better than that of the ordinary commercial ceramic filters, which was of obvious advantages and development prospects. The results have provided reference for the practical engineering and theoretical study.

       

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