张红涛, 陆军, 魏德云, 胡玉霞. 烷基聚葡糖苷液滴在黄瓜叶面的润湿状态及动态铺展行为[J]. 农业工程学报, 2017, 33(3): 81-87. DOI: 10.11975/j.issn.1002-6819.2017.03.011
    引用本文: 张红涛, 陆军, 魏德云, 胡玉霞. 烷基聚葡糖苷液滴在黄瓜叶面的润湿状态及动态铺展行为[J]. 农业工程学报, 2017, 33(3): 81-87. DOI: 10.11975/j.issn.1002-6819.2017.03.011
    Zhang Hongtao, Lu Jun, Wei Deyun, Hu Yuxia. Wetting state and dynamic spreading behavior of alkyl polyglycoside drop on cucumber leaf surface[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2017, 33(3): 81-87. DOI: 10.11975/j.issn.1002-6819.2017.03.011
    Citation: Zhang Hongtao, Lu Jun, Wei Deyun, Hu Yuxia. Wetting state and dynamic spreading behavior of alkyl polyglycoside drop on cucumber leaf surface[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2017, 33(3): 81-87. DOI: 10.11975/j.issn.1002-6819.2017.03.011

    烷基聚葡糖苷液滴在黄瓜叶面的润湿状态及动态铺展行为

    Wetting state and dynamic spreading behavior of alkyl polyglycoside drop on cucumber leaf surface

    • 摘要: 为了探究烷基聚葡糖苷(alkyl polyglycosid,APG)在黄瓜叶面的动态润湿行为及其动态接触角变化规律,采用表面张力与接触角测量仪测量了一次去离子水和9种质量百分数APG水溶液(14.35%~85.78%)的表面张力、液滴叶面接触角与动态接触角、前进角与后退角、铺展直径等动态润湿参数。依据Tanner法则对接触角滞后现象、铺展驱动力成因进行分析和推测,并应用幂次法则拟合了铺展直径与幂值和时间的关系曲线。结果表明,9种APG水溶液的表面张力介于27.96~29.73 mN/m小幅范围内,而接触角却在11.35°~34.20°较大范围内变化;接触角滞后性(Δθ=46.89°)较大,反映出一次去离子水在活体植物黄瓜叶面的接触角变化符合粗糙表面上接触角滞后现象的基本规律;各质量百分数APG溶液的动态接触角在前1 s内急速下降,在之后1~10 s平稳减小并渐趋于稳定;APG在黄瓜叶面的铺展直径与时间的关系均较好地符合幂次法则,据此推测动态表面张力是黄瓜叶面(界面)占据绝对优势的铺展驱动力。

       

      Abstract: Abstract: Improving the wettability of spraying liquid on the target crop surface is one of the effective ways for enhancing the utilization efficiency of pesticide. When the spray liquid reached the surface of target crop, will occur series dynamic process including deposition, retention, spread, penetration, etc. These behaviors of dynamic wetting will decide spraying liquid how to transfer to biological organisms, and make directly influence of the pesticide. As entering the 21st century, the dynamic wetting behavior of liquid on target interface has become a very active research direction in the pesticide application field, which is one of the important research contents of precision spraying technology. Alkyl Polyglycoside (APG) is recognized as an internationally preferred green functional surfactant, it has attracted special attention because of its high surface activity and ecological security. In recent years, more and more domestic and foreign researchers have done a lot of work in improving APG pesticide additives, which focusing on the preparation, modification and its synergism mechanism, and achieved obvious achievements. In order to investigate the dynamic wetting behavior of APG additive solution on the cucumber leaf surface and its change of dynamic contact angle, APG solution of 9 mass fraction (14.35%-85.78%) and their dynamic wetting parameters which includes surface tension (γ), contact angle (θ), dynamic contact angle (θd), advancing contact angle (θa), receding contact angle (θr), spreading diameter (Φ) were measured by using surface tension and contact angle measuring instrument based on hanging drop method and sessile drop method. The contact angle hysteresis and spreading driving force are analyzed and deduced based on Tanner rule, and the relationship curve between spreading diameter (Φ), power value (α) and time (t) were fitted by the application of the power law. With digital image processing technology, the process of dynamic wetting was recorded by CCD camera and their dynamic wetting parameters were obtained and extracted from drop images features. The results showed that these 9 APG solutions' surface tension were within a narrow range from 27.96 to 29.73 mN·m?1, but their contact angle were varied from 11.35° to 34.20° in a wide range. It indicated contact angles did not change radically with the increasing concentration of APG solution. As a kind of easily wetting leaves, advancing contact angle (θa) of deionized water drop on cucumber leaf surface increased by 7.54°, while receding contact angle (θr) decreased by 22.85°, its contact angle hysteresis (Δθ) is 46.89° within 10 s. The dynamic wetting process reflects the interface behavior of cucumber leaves accords with the basic law of rough surface contact angle hysteresis. Dynamic contact angle of APG solution of different mass fraction on cucumber leaf surface fell sharply in the first 1 s, then decreased steadily and gradually tended to be stable (1-10 s). The relationship between the spreading diameter (Φ) and time (t) were better conformed to the power law. The power value of APG solution fitting curves were within the range from 0.01 to 0.08, the coefficient C were between 2.787 3 and 3.567 3, the APG solution of lower concentration showed a higher fitting degree. It can be inferred that the dynamic surface tension is the dominant spreading driving force on cucumber leaf surface (interface). This paper provides theoretical basis and technical support for pesticide spraying with cucumber as target crop and APG as adjuvant.

       

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