黎演明, 黄志民, 龙思宇, 韦光贤, 李俊晓. 添加适量菌棒废渣提高桑枝颗粒燃料成型率及改善燃烧性能[J]. 农业工程学报, 2015, 31(19): 216-221. DOI: 10.11975/j.issn.1002-6819.2015.19.030
    引用本文: 黎演明, 黄志民, 龙思宇, 韦光贤, 李俊晓. 添加适量菌棒废渣提高桑枝颗粒燃料成型率及改善燃烧性能[J]. 农业工程学报, 2015, 31(19): 216-221. DOI: 10.11975/j.issn.1002-6819.2015.19.030
    Li Yanming, Huang Zhiming, Long Siyu, Wei Guangxian, Li Junxiao. Optimum mushroom planted residual as briquetting binder in ramulus mori pellet fuel improving their modeling ratio and combustion properties[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2015, 31(19): 216-221. DOI: 10.11975/j.issn.1002-6819.2015.19.030
    Citation: Li Yanming, Huang Zhiming, Long Siyu, Wei Guangxian, Li Junxiao. Optimum mushroom planted residual as briquetting binder in ramulus mori pellet fuel improving their modeling ratio and combustion properties[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2015, 31(19): 216-221. DOI: 10.11975/j.issn.1002-6819.2015.19.030

    添加适量菌棒废渣提高桑枝颗粒燃料成型率及改善燃烧性能

    Optimum mushroom planted residual as briquetting binder in ramulus mori pellet fuel improving their modeling ratio and combustion properties

    • 摘要: 对桑枝(ramulus Mori,RM)和菌棒废渣(mushroom-planted residue,MPR)进行了工业分析、元素分析、生物质三组分以及空气干燥基低位发热量值分析。从RM和MPR中分别提取了木质素,通过DSC测定了其玻璃化转变温度。结果表明RM的挥发分含量、低位发热量值和玻璃化转变温度较高,分别为72.54%,17.57 MJ/kg和160.6℃;MPR的挥发分含量、低位发热量值和玻璃化转变温度分别为66.72%、15.23 MJ/kg和136.8℃,通过单因素方差分析表明其与RM存在极显著差异。该研究通过在RM中分别添加5%~20%质量分数的MPR作为黏结剂,采用4 mm孔径振动筛控制颗粒度,在含水率为20%±0.5%以及可变的环模孔长孔长径比条件下,通过压辊环模成型机制备了RM/MPR复合颗粒燃料。结果表明在环模孔长径比为4:1时,RM不能有效的致密化,颗粒成型率仅为50.24%。MPR具有更好的流动性和黏结性,可作为黏结剂将RM纤维粘结于一起,增加一定质量比例的MPR可以提高RM颗粒成型率。在环模孔长径比为4:1时,随着MPR的添加量增加至10%~15%,RM/MPR复合颗粒燃料的成型率大于91.54%。在MPR的添加量在5%~20%范围内,RM/MPR复合颗粒燃料的密度、耐久率以及燃烧值分别高于1.208,96.42%和17.26 MJ/kg,符合生物质燃料要求。

       

      Abstract: Abstract: A mass of Ramulus Mori (RM), Mushroom Planted Residual (MPR) are generated from sericulture and mushroom planting industries in China every year. After adequate drying and densification, these residues can be used as alternative raw materials of pellet fuel for heat generation. RM and MPR differ from crop stalks and sawdust for their physical characteristics and chemical composition. In order to produce high-quality pellet fuel from such materials,it is necessary to understand the role of these variations. The RM and MPR ( Main components: 85% Ramulus Mori, 12% cassava alcohol residues, 2% calcium oxide and 1% calcium sulfate) were tested for moisture content, net calorific value in air dried basis, contents of ash, volatile, fixed carbon, carbon, hydrogen, oxygen, nitrogen, sulphur and three biomass components (cellulose, hemicellulose and lignin). Also the glass transition temperature of two types of lignin which were extracted from RM and MPR, respectively, were determined by differential scanning calorimetry (DSC). The results showed that RM had low ash, sulfur and nitrogen content, but high volatile, net calorific value and glass transition temperature at 72.54%, 17.57 MJ/kg and 160℃, respectively, implying that RM was an excellent raw material for pellet fuel production, especially if the pressure and temperature during its pelletization can be controlled. The volatile, net calorific value and glass transition temperature of MPR were 66.72 %, 15.23 MJ/kg and 136.8℃, respectively, which were very significantly different from those of RM by univariate variance statistical analysis. Compared with RM, MPR had lower content of cellulose, hemicellulose and lignin. These results showed that the single MPR was not a suitable raw material for pellet fuel production, but an excellent briquetting binder. MPR was mixed with RM as a briquetting binder when the percentages of MPR content were 5%, 10%, 15%, 20%, respectively. The composites were grounded by vibrating screen (constant size at 4 mm) and conditioned at constant moisture contents (20%±0.5%). Then the pelletization tests were carried out by using a ring die pellet mill with different length-diameter ratio of ring dies. Therefore, the influence of the length-diameter ratio of ring dies and the mass ratio of RM/MPR on the pelletizing-molding ratio and some mechanical properties (density, durability, net calorific value, etc.) of RM/MPR composite pellets were analyzed. The result showed that the single RM cannot be densified effectively to produce durable pellets when length-diameter ratio of ring die was 4:1, and the pelletizing-molding ratio of single RM was low at 50.24%. One of the methods to increase the pelletizing-molding ratio was to increase the length-diameter ratio of ring dies. The pelletizing-molding ratio of single RM rose to 95.67% when the length-diameter ratio of ring die increased to 5.5:1, but working with such length-diameter ratio of ring die, the ring die pellet mill could be damaged easily. Another effective method to increase the pelletizing-molding ratio was to increase the mass proportion of MPR in the composites. During pelletizing process, MPR can be used as a briquetting binder to connect RM fibers due to its good performance of liquidity and cohesiveness. When mass proportion of MPR in the composites increased to 10% or 15%, the pelletizing-molding ratio of RM/MPR composite pellets was more than 91.54% with length-diameter ratio of ring die at 4:1. The density and durability of the RM/MPR composite pellets were enhanced when a small amount of MPR was added, which indicated that the mass proportion of MPR was proportional to density and durability of RM/MPR composite pellets. Meanwhile, RM/MPR composite pellets showed a satisfying value on net calorific value due to its volatility. When the mass proportion of MPR in the mixture was be within 0-20%, the density, durability and net calorific value of RM/MPR composite pellets was more than 1.208, 96.42% and 17.26 MJ/kg, respectively, which met the criteria of biomass pellet fuel.

       

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