吕 杰, 郝宁燕, 崔晓临. 利用可见光近红外的尾矿区农田土壤Cu含量反演[J]. 农业工程学报, 2015, 31(9): 265-270. DOI: 10.11975/j.issn.1002-6819.2015.09.040
    引用本文: 吕 杰, 郝宁燕, 崔晓临. 利用可见光近红外的尾矿区农田土壤Cu含量反演[J]. 农业工程学报, 2015, 31(9): 265-270. DOI: 10.11975/j.issn.1002-6819.2015.09.040
    Lü Jie, Hao Ningyan, Cui Xiaolin. Inversion model for copper content in farmland of tailing area based on visible-near infrared reflectance spectroscopy[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2015, 31(9): 265-270. DOI: 10.11975/j.issn.1002-6819.2015.09.040
    Citation: Lü Jie, Hao Ningyan, Cui Xiaolin. Inversion model for copper content in farmland of tailing area based on visible-near infrared reflectance spectroscopy[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2015, 31(9): 265-270. DOI: 10.11975/j.issn.1002-6819.2015.09.040

    利用可见光近红外的尾矿区农田土壤Cu含量反演

    Inversion model for copper content in farmland of tailing area based on visible-near infrared reflectance spectroscopy

    • 摘要: 矿山开采普遍存在土壤重金属污染问题,有效的进行尾矿区农田土壤重金属含量估算迫在眉睫。以陕西金堆城矿区尾矿为研究区,采集土壤样本,测量土壤可见光近红外光谱,测试分析土壤铜元素含量。将Isomap(Isometrio mapping)和LLE(locally linear embedding)流形学习方法应用于土壤高光谱降维,基于随机森林构建估算模型,反演土壤铜含量。结果表明:降维后的高光谱数据反演精度更高,Isomap降维后模型预测结果均方根误差为30.50,R2=0.76,优于LLE降维结果。研究为尾矿区土壤Cu元素含量的快速反演估算提供了理论依据。

       

      Abstract: Abstract: Heavy metal pollution exists in many mining sites, and heavy metal in soils poses a great potential threat to the environment and human health. Therefore, it is urgent to estimate heavy metals in farmland in tailing areas of mining sites. The goal of this research was to estimate copper content in farmland of a tailing area based on visible-near infrared reflectance spectroscopy. This research took Jinduicheng mine tailings in Shaanxi as the study area. A total number of 288 soil samples were collected at the mining areas. The soil samples were divided into two groups, a training/calibration set (n=252) and an external validation set (n=36) for the Cu estimation model. The soil samples were air dried and passed through a 2 mm sieve. The Cu concentrations in soil were determined through chemical analysis in the laboratory by graphite furnace atomic absorption spectrometry (GB/T17141-1997). The visible-near infrared reflectance spectral measurements of soil Cu concentration were collected using an ASD field spectrometer for the solar reflective wavelengths (350-2500 nm) in the laboratory. The 8 angle probe was used, the distance from the contact probe to the surface of soil samples was set to 1.35 m in order to get the soil spectral in the range of 1 m2, and each soil sample was achieved 10 spectral measurements. The original reflectance was transformed with a db6 wavelet analysis. The Isomap (Isometrio Mapping) and LLE (Locally Linear Embedding) manifold learning methods were applied to the hyperspectral data of soil for dimension reduction, parameter of k and d was 10 to 50 and 8-15, respectively. Copper concentration in the mine tailing soil was estimated by the method of random forests. The estimated results were compared with the original hyperspectral data and the dimension reduction spectral data. The results showed that the spectral characteristics of the most important values were at the wavelength of 475 802, and 868 nm. The estimation model had a better performance on dimension reduction spectral data set than that on the original spectral data set, and the estimation model achieved coefficient of determination R2 of 0.7586 on the spectral data set after dimension reduced by Isomap, and the RMSE (root mean square error) was 30.50, the estimation accuracy was better than that on the dimension reduction by LLE, but the accuracy needed to be improved. The results provide a theoretical basis for rapid estimation copper content of farmland soil in the tailing area, and will provide theoretical basis and technological support for controls of mining tailings and mining wasteland and its ecological restoration and reconstruction.

       

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